A five-wicket haul on his 100th Test by Ashwin India won by an innings and 64 runs, seal series by 4-1.
Indian lower order Kuldeep Yadav and Jasprit Bumrah shared a partnership faced 108 deliveries.
England already face an uphill battle to salvage a final win from their tour of India after an awful batting collapse on day one of the fifth Test in Dharamsala.
Chasing 192, India went from 84/0 to 120/5 before Shubman Gill and Dhruv Jurel guided them home for a five-wicket win.
Dhruv Jurel scores fighting 90 inspired India comeback.
Shoaib Bashir pick-up wonderful 4-84 gave England a golden opportunity to take control of the fourth Test against India in Ranchi.
Veteran batter stepped in and took control shepherding his team from 112 for 5 to 302 for 7 by stumps.
England slide to a dismal 434-run defeat by India on the fourth day of the third Test in Rajkot.
The hosts had moved to 196-2, 322 ahead and primed to take a 2-1 lead in the series.
A sensational century by Ben Duckett, at 88 balls the fastest against India, left the hosts shell-shocked in Rajkot.